An exopolyhedral cyclized platinaundecaborane [(PPh3)(PhCOS)PtB10H9(PPh3)].-1.5CHCl(3)

Citation
Ch. Hu et al., An exopolyhedral cyclized platinaundecaborane [(PPh3)(PhCOS)PtB10H9(PPh3)].-1.5CHCl(3), ACT CRYST C, 54, 1998, pp. 1835-1837
Citations number
18
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
54
Year of publication
1998
Part
12
Pages
1835 - 1837
Database
ISI
SICI code
0108-2701(199812)54:<1835:AECP[>2.0.ZU;2-X
Abstract
The title platinaundecaborane species, 7,11-(mu-thiobenzoato-S:O)-7,10-bis( triphenylphosphine-P)-8:9-mu H-7-platina-nido-undecaborane-chloroform (1/1. 5), has a nido-type {PtB10} cage with a five-membered Pt-S-C-O-B ring. Of t he two PPh3 ligands, one is bound to the Pt atom and the other to a B atom.