[N-(3-aminopropyl)-N-methyl-1,3-propanediamine-kappa N-3]dichlorocopper(II)

Authors
McCasland, AK Alcock, NW Busch, DH
Citation
Ak. Mccasland et al., [N-(3-aminopropyl)-N-methyl-1,3-propanediamine-kappa N-3]dichlorocopper(II), ACT CRYST C, 54, 1998, pp. 1837-1839
Citations number
16
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
54
Year of publication
1998
Part
12
Pages
1837 - 1839
Database
ISI
SICI code
0108-2701(199812)54:<1837:[N>2.0.ZU;2-O
Abstract
The preparation and crystal structure of the title complex, [CuCl2(C7H19N3) ], are described. The Cu-II ion has distorted tetragonal pyramidal geometry , with Cl axial; the axial Cu-Cl distance [2.505 (1) Angstrom] is elongated compared with the basal Cu-Cl distance [2.400 (1) Angstrom]. In the basal plane, Cu-N(tertiary) [2.138 (3) Angstrom] is considerably longer than Cu-N (primary) [1.985 (4) Angstrom mean], presumably reflecting the reduced basi city of the ligand atom.