Bis(triethylsulfonium) tetraiodomercurate(II)

Citation
L. Bengtsson-kloo et al., Bis(triethylsulfonium) tetraiodomercurate(II), ACT CRYST C, 54, 1998, pp. 1851-1853
Citations number
19
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
54
Year of publication
1998
Part
12
Pages
1851 - 1853
Database
ISI
SICI code
0108-2701(199812)54:<1851:BT>2.0.ZU;2-W
Abstract
The reaction of an aqueous slurry of HgI2 and an acetone solution of (Et3S) I (molar ratio 1:2) gives the title compound, [(C2H5)(3)S](2)[HgI4], which contains discrete pyramidal Et3S+ and tetrahedral HgI42- ions. The bond dis tances of the anion (Hg1-I1 and Hg1-I2) are 2.780 (1) and 2.790 (1) Angstro m.