1,9a-epoxy-1,2,3,4,4a,4b,5,8,8a,9a-decahydro-2-methyl-4-nitro-5,8-methano-9H-fluoren-9-one

Citation
Hk. Fun et al., 1,9a-epoxy-1,2,3,4,4a,4b,5,8,8a,9a-decahydro-2-methyl-4-nitro-5,8-methano-9H-fluoren-9-one, ACT CRYST C, 54, 1998, pp. 1925-1927
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
54
Year of publication
1998
Part
12
Pages
1925 - 1927
Database
ISI
SICI code
0108-2701(199812)54:<1925:1>2.0.ZU;2-M
Abstract
The six-membered ring of the title compound, C15H17NO4, adopts a half-chair conformation, and the methyl and nitro groups are attached equatorially to it. The five-membered ring fused to it is in a fattened envelope conformat ion. In the norbornene ring system, the six-membered ring adopts a fairly s ymmetrical boat conformation and the two five-membered rings formed by the bridging C atom adopt envelope conformations. The mean plane through the fu sed five-membered ring forms dihedral angles of 31.14(5) and 84.28(7)degree s with the mean planes of the adjacent six-membered rings.