Epiclusianone: a new natural product derivative of bicyclo[3.3.1]nonane-2,4,9-trione

Authors
Santos, MH Speziali, NL Nagem, TJ Oliveira, TT
Citation
Mh. Santos et al., Epiclusianone: a new natural product derivative of bicyclo[3.3.1]nonane-2,4,9-trione, ACT CRYST C, 54, 1998, pp. 1990-1992
Citations number
7
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
54
Year of publication
1998
Part
12
Pages
1990 - 1992
Database
ISI
SICI code
0108-2701(199812)54:<1990:EANNPD>2.0.ZU;2-T
Abstract
Epiclusianone [3-benzoyl-4-hydroxy-6,6-dimethyl-1,5,7-tris(3-methyl-2-buten yl)bicyclo[3.3.1]non-3-ene-2,9-dione] is a new isomeric form of the C33H42O 4 compound identified by X-ray diffraction analysis. Structure comparison w ith the known clusianone evidences a case of epimerism in one of the chiral C atoms. A comparison of the melting point and the optical activity of the two isomers shows them to have different values.