The adsorption structures and growth of Al on Si(100) have been intensively
studied using scanning tunneling microscope (STM). The high-resolution STM
images are presented to demonstrate that the Al-adsorbed Si(100) surface i
s accurately described by the parallel-dimer model, The structures at the e
nds of Al dimer rows are further discussed by means of the illustration of
STM images taken from the occupied and unoccupied electronic state surfaces
. The dimer termination is confirmed to be a stable structure at the end of
an Al dimer row. Moreover, the growth behavior of Al on the Si(100) surfac
e with coverages over 0.5 monolayer (ML) are also investigated on the basis
of STM observations as a function of the Al coverage up to 1.4 ML. The STM
images reveal that once a well-ordered Al 2 x 2 adlayer is formed at 0.5 M
L, further deposition of Al results in the disappearance of the Al 2 x 2 ph
ase without disruption of the Si 2 x 1 reconstruction.