Nanoscale materials and their properties are mainly defined by the interfac
e material and its properties. The charge transfer in those materials, i.e.
, across and along interfaces is complex. In contrast to classical charge t
ransfer via direct tunneling dying away quickly in 0.5 nm, most charges are
transferred at interfaces via resonant tunneling and higher-order intermed
iate state tunneling bridging 2-25 nm. The basic concepts of this incoheren
t charge transfer are presented and known intermediate states are elucidate
d and model systems are discussed.