Unstrained Ga0.64In0.36As0.84Sb0.16/InP single quantum-well structures were
grown on InP substrates by metalorganic vapor phase epitaxy. Transmission
electron microscopy and temperature-dependent photoluminescence (PL) measur
ements were performed. The valence-band offset of the GaInAsSb/InP heteroju
nction was estimated by the dependence of PL peak energy on the well width
at 8 K. We estimated the valence-band offset to be 70+/-5% of the band-gap
difference for the Ga0.64In0.36As0.84Sb0.16/InP heterostructure. (C) 1999 A
merican Institute of Physics. [S0003-6951(99)03405-1].