Pulsed laser deposition technique is very well suited for thin film prepara
tion of multicomponent oxides. It has been applied to the deposition of sup
erconductor, ferroelectric and electrooptics oxides. The main advantages of
the technique are briefly summarised in this review, moreover some physica
l mechanisms leading to a film composition departure from the target one ar
e analysed. Particular attention is paid on the laser-induced modification
of the target, scattering in the plume, film diffusion into the substrate a
nd reevaporation from the film. These phenomena are illustrated with niobat
e and lead titanate oxides. The proper understanding of these phenomena all
ows the optimisation of the deposition parameters to achieve specific cryst
alline films suited for some microelectronics and optical applications.