Thin films of CuGaxIn1-xSe2 (x=0.0-1.0) have been prepared by spray pyrolys
is onto soda-lime glass substrates heated to a temperature of 325 degrees C
. The structure, crystal orientations, lattice parameters and grain size of
the experimental films have been studied using the X-ray diffraction and s
canning electron microscopy. All the deposited films were polycrystalline a
nd showed single phase with an intense (112) orientation. The lattice param
eters, a and c of the films vary linearly with the change of gallium compos
ition. The grain size of the films decrease with the increase of gallium co
ntent.