The principles of scanning electrochemical microscopy (SECM) will be b
riefly introduced, and recent advances using this technique will be di
scussed. Recent studies from our group using SECM include the characte
rization of thin films, using the SECM in combination with a quartz-cr
ystal microbalance; the detection of single molecules; the determinati
on of electron-transfer rates the interface between two immiscible ele
ctrolyte solutions; and the measurement of the kinetics of ECE and DIS
P1 reactions.