SPECTROSCOPIC BEHAVIOR OF K-3[CR(NCS)(6)] COMPLEXES ENTRAPPED IN SILICA GLASSES OBTAINED BY THE SOL-GEL METHOD

Authors
MARUSZEWSKIA K DEREN P LUKOWIAK E NISSENSOBOCINSKA B STREK W TRABJERG I
Citation
K. Maruszewskia et al., SPECTROSCOPIC BEHAVIOR OF K-3[CR(NCS)(6)] COMPLEXES ENTRAPPED IN SILICA GLASSES OBTAINED BY THE SOL-GEL METHOD, Journal of molecular structure, 404(1-2), 1997, pp. 137-140
Citations number
7
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular structure → ACNP
ISSN journal
00222860
Volume
404
Issue
1-2
Year of publication
1997
Pages
137 - 140
Database
ISI
SICI code
0022-2860(1997)404:1-2<137:SBOKCE>2.0.ZU;2-G
Abstract
K-3[Cr(NCS)(6)] complex samples entrapped in silica glass were prepare d by the sol-gel technique. It has been noticed that the original colo r of the complex changed gradually from violet to green upon entrapmen t. This process occurred within several days. Electronic absorption an d emission spectra obtained during this process, along with the severa l chemical experiments performed, indicate that the sol-gel matrix ind uces an exchange of the NCS- ligand with ammonia. (C) 1997 Elsevier Sc ience B.V.