CF4 and the age of mesospheric and polar vortex air

A chronology of tropospheric CF4 mixing ratios is reported for the northern hemisphere, A decline of global emissions of CF4 from 16,000 to 11,000 met ric tons yr(-1) is found for the periods 1978-1990 and 1992-1998, respectiv ely. The atmospheric chronology of CF4 is applied to determine the age of a ir of cryogenic air samples collected on rocket and balloon platforms. Age values of 7 years are found inside the polar vortex between 25-44 km altitu de and of 11 years between 56 and 61 km altitude, which is significantly hi gher than predicted by most models currently used to assess the effects of high-flying aircraft. The results suggest that the mesosphere is more isola ted from below than previously believed. A comparison of age values derived from CF4 and SF6 relative to predicted deviations constrains the atmospher ic lifetime of SF6 to >5,000 years.