Deboronation of HB(3,5-Me2C3HN2)(3)(-) in a reaction with [Re(O)Cl-4](-), the X-ray crystal structures of [{Re(O)Cl(3,5-Me2C3HN2H)(3)}-(mu-O){Re(O)Cl-3(3,5-Me2C3HN2H)}] and [{Re(O)Cl-2(3,5-Me2C3HN2H)(2)}(mu-O){Re(O)Cl-2(3,5-Me2C3HN2H)(2)}]

Authors
Hinton, HA Chen, HL Hamor, TA McQuillan, FS Jones, CJ
Citation
Ha. Hinton et al., Deboronation of HB(3,5-Me2C3HN2)(3)(-) in a reaction with [Re(O)Cl-4](-), the X-ray crystal structures of [{Re(O)Cl(3,5-Me2C3HN2H)(3)}-(mu-O){Re(O)Cl-3(3,5-Me2C3HN2H)}] and [{Re(O)Cl-2(3,5-Me2C3HN2H)(2)}(mu-O){Re(O)Cl-2(3,5-Me2C3HN2H)(2)}], INORG CHIM, 285(1), 1999, pp. 55-59
Citations number
39
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
285
Issue
1
Year of publication
1999
Pages
55 - 59
Database
ISI
SICI code
0020-1693(19990202)285:1<55:DOHIAR>2.0.ZU;2-F
Abstract
A modified synthetic route to [Re(O)(tp*)Cl-2] {tp* =HB(3.5-Me2C3HN2)(3)} f rom Re2O7 is described. The reaction between Bu4N[Re(O)Cl-4] and Ktp* affor ds, as its main product, the unsymmetrically substituted binuclear ore-brid ged complex [{Re(O)Cl(3,5Me(2)C(3)HN(2)H)(3)}(mu-O) {Re(O)Cl-3(3,5-Me2C3HN2 H)}] (1) together with some of the known symmetrically substituted isomer [ {Re(O)Cl-2(3,5-Me2C3HN2H)(2)}(mu-O) {Re(O)Cl-2(3.5-Me2C3HN2H)(2)}] (2). Bot h isomers were characterised by single crystal X-ray diffraction studies of the CH2Cl2 solvates. (C) 1999 Elsevier Science S.A. All rights reserved.