Citation
Ma. Beswick et al., Synthesis and structure of [{As-2(NCy)(4)}(2)Li-4], containing an imido As(III) dianion, J CHEM S DA, (2), 1999, pp. 107-108
Citations number
10
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
03009246
→ ACNP
Issue
2
Year of publication
1999
Pages
107 - 108
Database
ISI
SICI code
0300-9246(19990121):2<107:SASO[C>2.0.ZU;2-T
Abstract
Reaction of [As(NMe2)(3)] with CyNH2 (1:1 equivalents), followed by the add
ition of [CyNHLi] (1 equivalent) gives the heterobimetallic cage complex [{
As-2(NCy)(4)}(2)Li-4] the first example of a complex containing an imido As
(III) anion; the missing link in a series of Group 15 anions of the type [{
E-2(NCy)(4)}](2-) (E = Bi, Sb and P).