Ch. Wang et al., The capacitive drop tensiometer - a novel multianalysing technique for measuring the properties of liquids, MEAS SCI T, 10(1), 1999, pp. 19-24
A new instrumental method for measuring the physical properties of a liquid
has been developed. The instrument, called a capacitive drop tensiometer (
CDT), is based on the drop volume principle in combination with a capacitiv
e transducer. A delivery head with a specialized wetting design was constru
cted for forming drops. The capacitive transducer uses the delivery head as
one of its plates and a cylindrical ring plate, which surrounds the delive
ry head and the space occupied by the drop that is formed, as another. Exce
llent linearity is achieved by optimizing the design, with an accuracy of d
rop volume measurement of approximately 2 mu l. The system is suitable for
measuring both drops in equilibrium and those in the process of growing. It
s capability of real-time measurement makes it particularly useful for vola
tile liquids, in which instance the measurement of drop volume using a flow
meter or a pump is no longer reliable. The CDT can also be used to determin
e concentration. It was found that the concentration curve is linear for aq
ueous glycerol solutions although not so for aqueous ethanol solutions. The
CDT's ability to measure surface tension was also explored and experimenta
l results are presented here.