Citation
Yg. Shermolovich et al., Synthesis of difluorodithiopyruvic acid derivatives, MENDELEEV C, (6), 1998, pp. 245-246
Citations number
11
Categorie Soggetti
Chemistry
Journal title
MENDELEEV COMMUNICATIONS
ISSN journal
09599436
→ ACNP
Issue
6
Year of publication
1998
Pages
245 - 246
Database
ISI
SICI code
0959-9436(199811):6<245:SODAD>2.0.ZU;2-T
Abstract
The reaction of cadmium sulfide with 1,1-dichloro-3,3-difluoro-2-oxo-1-prop
ylthiopropane yields difluorodithiopyruvic propionate. This reacts with mor
pholine to give difluorodithiopyruvic morpholide; it also undergoes a cyclo
addition reaction to the carbon-sulfur double bond with dimethylbutadiene t
o form 2-difluoroacetyl-4,5-dimethyl-2-propylthio-3H,6H-thiopyran.