An off-limb scan of Callisto was conducted by the Galileo near-infrared map
ping spectrometer to search for a carbon dioxide atmosphere. Airglow in the
carbon dioxide nu(3) band was observed up to 100 kilometers above the surf
ace and indicates the presence of a tenuous carbon dioxide atmosphere with
surface pressure of 7.5 x 10(-12) bar and a temperature of about 150 kelvin
, close to the surface temperature. A lifetime on the order of 4 years is s
uggested, based on photoionization and magnetospheric sweeping. Either the
atmosphere is transient and was formed recently or some process is currentl
y supplying carbon dioxide to the atmosphere.