Annealed W (WN)/4H-SiC interfaces have been compared on the basis of X-ray
photoelectron spectroscopy (XPS) studies. The 1200 degrees C annealed W (WN
)/4H-SiC structures are characterized by intense interface reactions leadin
g to tungsten carbide and tungsten silicide formation in the contact layers
. The 800 degrees C annealed WN/4H-SiC structure exhibits a chemically iner
t interface, and the 800 degrees C annealed WN/4H-SiC contact is found to b
e of a Schottky type with a barrier height of 0.94 eV and an ideality coeff
icient of 1.09. (C) 1999 Elsevier Science S.A. All rights reserved.