SYNTHESIS AND REACTIVITY OF PHOSPHIRANE LIGANDS AND THE STRUCTURAL CHARACTERIZATION OF CP-ASTERISK-IRCL2(TERT-BUTYLPHOSPHIRANE)

Authors
MEZAILLES N FANWICK PE KUBIAK CP
Citation
N. Mezailles et al., SYNTHESIS AND REACTIVITY OF PHOSPHIRANE LIGANDS AND THE STRUCTURAL CHARACTERIZATION OF CP-ASTERISK-IRCL2(TERT-BUTYLPHOSPHIRANE), Organometallics, 16(8), 1997, pp. 1526-1530
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
8
Year of publication
1997
Pages
1526 - 1530
Database
ISI
SICI code
0276-7333(1997)16:8<1526:SAROPL>2.0.ZU;2-M
Abstract
New and stable phosphiranes, tert-butylphosphirane and xylylphosphiran e, were prepared. tert-Butylphosphirane is stable to polymerization in the presence of electrophiles. It was reacted with chloro)chloro(pent amethylcyclopentadienyl)iridium) to prepare rane)dichloro(pentamethylc yclopentadienyl)iridium, which was characterized by X-ray diffraction, tert-Butylphosphirane was also reacted with pentacarbonyl(tetrahydrof uran)tungsten and borane to form (tert-butylphosphirane)pentacarbonylt ungsten and the first phosphirane-borane adduct, respectively.