REACTION OF THE RMGX FE(CO)(5)/CUCL SYSTEM WITH ALKYNES - NOVEL DOUBLE CARBONYLATION LEADING TO BUTENOLIDES AND CYCLOBUTENEDIONE/

Authors
RADHAKRISHNAN U PERIASAMY M
Citation
U. Radhakrishnan et M. Periasamy, REACTION OF THE RMGX FE(CO)(5)/CUCL SYSTEM WITH ALKYNES - NOVEL DOUBLE CARBONYLATION LEADING TO BUTENOLIDES AND CYCLOBUTENEDIONE/, Organometallics, 16(8), 1997, pp. 1800-1802
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
8
Year of publication
1997
Pages
1800 - 1802
Database
ISI
SICI code
0276-7333(1997)16:8<1800:ROTRFS>2.0.ZU;2-5
Abstract
Reaction of RMgX with Fe(CO)(5) and CuCl leads to the formation of 1,2 -diketones in moderate yields. The reagent system gives the correspond ing butenolides and cyclobutenedione in the presence of alkynes.