DYNAMIC STEREOCHEMISTRY OF TERMINALLY SUBSTITUTED PI-ALLYL COMPLEXES OF MOLYBDENUM WITH THE TP' LIGAND - NMR EVIDENCE FOR PI-SIGMA-PI INTERCONVERSION

Authors
CHOWDHURY SK NANDI M JOSHI VS SARKAR A
Citation
Sk. Chowdhury et al., DYNAMIC STEREOCHEMISTRY OF TERMINALLY SUBSTITUTED PI-ALLYL COMPLEXES OF MOLYBDENUM WITH THE TP' LIGAND - NMR EVIDENCE FOR PI-SIGMA-PI INTERCONVERSION, Organometallics, 16(8), 1997, pp. 1806-1809
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
8
Year of publication
1997
Pages
1806 - 1809
Database
ISI
SICI code
0276-7333(1997)16:8<1806:DSOTSP>2.0.ZU;2-X
Abstract
NMR spectroscopic evidence is provided for a pi-sigma-pi interconversi on in fluxional, mono- and 1,3-disubstituted pi-allyl molybdenum compl exes containing the hydro tris(3, 5-dimethylpyrazolyl) borate ligand.