REACTIONS IN MICELLAR SOLUTIONS .15. FORMATION, ACID-CATALYZED AQUATION AND INTRAMOLECULAR ISOMERIZATION OF -S)-(SULFITO-O)(TETRAETHYLENEPENTAMINE)COBALT(III) IN AQUEOUS ANIONIC AND NONIONIC MICELLAR MEDIA - DRAMATIC ENHANCEMENT OF THE RATE OF ISOMERIZATION BY SODIUM DODECYL-SULFATE

Authors
DASH AC PATNAIK AK
Citation
Ac. Dash et Ak. Patnaik, REACTIONS IN MICELLAR SOLUTIONS .15. FORMATION, ACID-CATALYZED AQUATION AND INTRAMOLECULAR ISOMERIZATION OF -S)-(SULFITO-O)(TETRAETHYLENEPENTAMINE)COBALT(III) IN AQUEOUS ANIONIC AND NONIONIC MICELLAR MEDIA - DRAMATIC ENHANCEMENT OF THE RATE OF ISOMERIZATION BY SODIUM DODECYL-SULFATE, Journal of chemical research. Synopses, (6), 1995, pp. 230
Citations number
40
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses → ACNP
ISSN journal
03082342
Issue
6
Year of publication
1995
Database
ISI
SICI code
0308-2342(1995):6<230:RIMS.F>2.0.ZU;2-5
Abstract
Micelles of sodium dodecyl sulfate dramatically enhance the isomerisat ion of oxygen-bonded (sulfito) (tetren)cobalt(III) to its S-bonded for m while neutral and anionic micelles exert only marginal effects on th e reversible formation of this sulfito-O complex.