FURTHER-STUDIES ON THE STEREOCHEMISTRY OF SPARTEINE, ITS ISOMERS AND DERIVATIVES .24. 2-(P-TOLYL)SPARTEINE AND ITS MONOPERCHLORATE SALT

Authors
BOCZON W KOZIOL B
Citation
W. Boczon et B. Koziol, FURTHER-STUDIES ON THE STEREOCHEMISTRY OF SPARTEINE, ITS ISOMERS AND DERIVATIVES .24. 2-(P-TOLYL)SPARTEINE AND ITS MONOPERCHLORATE SALT, Journal of molecular structure, 403(3), 1997, pp. 171-181
Citations number
19
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular structure → ACNP
ISSN journal
00222860
Volume
403
Issue
3
Year of publication
1997
Pages
171 - 181
Database
ISI
SICI code
0022-2860(1997)403:3<171:FOTSOS>2.0.ZU;2-A
Abstract
Synthesis of 2-(p-tolyl)sparteine (VII), its monoperchlorate salt (VII -H+) as well as its deuterated analogs was performed. Their IR and C-1 3-NMR spectra were analysed to determine the structure of these compou nds and the substituent and protonation effects. Properties of VII wer e discussed on the basis of the analysis of the pK(MCS)' data. (C) 199 7 Elsevier Science B.V.