BOND-LENGTH VARIATIONS IN MOLECULES CONTAINING TRIPLE BONDS AND HALOGEN SUBSTITUENTS

Authors
STOLEVIK R POSTMYR L
Citation
R. Stolevik et L. Postmyr, BOND-LENGTH VARIATIONS IN MOLECULES CONTAINING TRIPLE BONDS AND HALOGEN SUBSTITUENTS, Journal of molecular structure, 403(3), 1997, pp. 207-211
Citations number
2
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular structure → ACNP
ISSN journal
00222860
Volume
403
Issue
3
Year of publication
1997
Pages
207 - 211
Database
ISI
SICI code
0022-2860(1997)403:3<207:BVIMCT>2.0.ZU;2-8
Abstract
Bond length variations in molecules containing the groups X-C=, X-C=C- CN, XH2C-C=, X2HC-C=, X3C-C=, XH2C-CH2-C, XH2C-CH2-CH2-C= and XH2C-CH2 -C= have been considered (X = F, Cl, Br, I). Missing values have been estimated on the basis of the systematic variations in bond lengths. T he X-C bond lengths have been compared with the corresponding bonds in halogen-substituted alkanes. Systematic trends have been pointed out. (C) 1997 Elsevier Science B.V.