T. Beck et A. Mosandl, gamma(delta)-Thionolactones - Enantioselective capillary GC and sensory characteristics of enantiomers, HRC-J HIGH, 22(2), 1999, pp. 89-92
The even numbered gamma(delta)-thionolactones (C-6-C-12) were investigated,
using heptakis(2,3-di-O-methyl-6-O-tert-butyldimethylsilyl)- and heptakis(
2,3-di-O-acetyl-6-O-tert- butyldimethylsilyl)-beta-cyclodextrin as chiral s
tationary phases in capillary gas chromatography. The odor characteristics
of gamma(delta)-thionolactone enantiomers were investigated by enantioselec
tive gas chromatography/olfactometry.