V. Cozzani et al., A NEW METHOD TO DETERMINE THE COMPOSITION OF BIOMASS BY THERMOGRAVIMETRIC ANALYSIS, Canadian journal of chemical engineering, 75(1), 1997, pp. 127-133
A method for the direct determination of the cellulose and lignin cont
ent of biomass has been developed. The method assumes that negligible
interactions exist between biomass macrocomponents and it is based on
the analysis of thermogravimetric (TG) pyrolysis data. The TG-weighed
sum method seems to be reliable and less time consuming than conventio
nal methods for the determination of the cellulose and lignin content.
Some limitations of the macrocomponent approach in the description of
biomass pyrolysis are also discussed. In particular, hemicellulose py
rolysis data are analyzed. The use of xylans as substitute materials f
or hemicellulose have been critically examined. The results obtained p
oint out that the widely practiced use of xylans as substitute compoun
ds for the simplified description of hemicellulose pyrolysis can lead
to significant errors.