An account is given of the research that has been carried out on mechanical
alloying/milling (MA/MM) during the past 25 years. Mechanical alloying, a
high energy ball milling process, has established itself as a viable solid
state processing route for the synthesis of a variety of equilibrium and no
n-equilibrium phases and phase mixtures. The process was initially invented
for the production of oxide dispersion strengthened (ODS) Ni-base superall
oys and later extended to other ODS alloys. The success of MA in producing
ODS alloys with better high temperature capabilities in comparison with oth
er processing routes is highlighted. Mechanical alloying has also been succ
essfully used for extending terminal solid solubilities in many commerciall
y important metallic systems. Many high melting intermetallics that are dif
ficult to prepare by conventional processing techniques could be easily syn
thesised with homogeneous structure and composition by MA. It has also, ove
r the years, proved itself to be superior to rapid solidification processin
g as a non-equilibrium processing tool. The considerable literature on the
synthesis of amorphous, quasicrystalline, and nanocrystalline materials by
MA is critically reviewed. The possibility of achieving solid solubility in
liquid immiscible systems has made MA a unique process. Reactive milling h
as opened new avenues for the solid state metallothermic reduction and for
the synthesis of nanocrystalline intermetallics and intermetallic matrix co
mposites. Despite numerous efforts, understanding of the process of MA, bei
ng far from equilibrium, is far from complete, leaving large scope for furt
her research in this exciting field.