M. Schaller et al., PB STEPWISE LEACHING (PBSL) DATING OF GARNET-ADDRESSING THE INCLUSIONPROBLEM, Schweizerische Mineralogische und Petrographische Mitteilungen, 77(1), 1997, pp. 113-121
The problem of monazite and zircon inclusions for garnet geochronology
has long been recognized. Both phases occur as (sub)microscopic inclu
sions in the majority of metamorphic garnets, and their presence can m
assively influence the budgets of U, Th, Pb and other elements and the
refore may strongly affect - if not dominate - the apparent age obtain
ed for the host mineral. Special care has to be taken if such inclusio
ns were formed during earlier events, as they are often highly retenti
ve for U,Th and Pb, and bulk garnet dating will give geologically mean
ingless mixing ages. To assess this critical issue we have selected th
ree garnets from different metamorphic terrains on which we per formed
Pb stepwise leaching (PbSL). We demonstrate that PbSL is potentially
successful (i) to detect micro-inclusions of monazite and zircon in ga
rnet by analyzing the step leaching Pb isotope spectra in the thorogen
ic vs uranogenic data array, (ii) to selectively and quantitatively re
move monazite-derived Pb from sufficiently fine-grained host garnet sp
lits and therefore to obtain monazite-free Pb-Pb isochron ages of the
host garnet, (iii) to assess whether or not inclusions were in isotope
equilibrium with their host as this crystallized, and subsequently (i
v) to constrain the approximate age of the interfering monazite and zi
rcon inclusions.