Theoretical and experimental investigations were conducted on the adsorptio
n characteristics of 1,1,1,2-tetrafluoroethane (HFC-134a) by granular and e
xtruded activated carbons (GAC and EAC). HFC-134a is currently regarded as
an excel-lent replacement for CFC-12 (Freon 12), a refrigerant previously u
sed in all automobiles and many cooling systems. Experimental results of co
lumn adsor-ption were employed to verify the theoretical breakthrough curve
s generated from the pro-posed model and excellent model fit of the breakth
rough curves of HCFC-134a adsorption were obtained. Investigations were als
o made on the effects of gas velocity, inlet HFC-134a concentration and ope
rating temperature on the adsorption efficiency.