Finite size scaling in quantum mechanics

Citation
P. Serra et al., Finite size scaling in quantum mechanics, J PHYS CH A, 102(47), 1999, pp. 9518-9522
Citations number
26
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF PHYSICAL CHEMISTRY A
ISSN journal
10895639 → ACNP
Volume
102
Issue
47
Year of publication
1999
Pages
9518 - 9522
Database
ISI
SICI code
1089-5639(19991119)102:47<9518:FSSIQM>2.0.ZU;2-C
Abstract
The finite size scaling ansatz is combined with the variational method to e xtract information about critical behavior of quantum Hamiltonians. This ap proach is based on taking the number of elements in a complete basis set as the size of the system. As in statistical mechanics, the finite size scali ng can then be used directly in the Schrodinger equation. This approach is general and gives very accurate results for the critical parameters, for wh ich the bound-state energy becomes absorbed or degenerate with a continuum. To illustrate the applications in quantum calculations, we present detaile d calculations for both short- and long-range potentials.