The use of freeze-gelation (or freeze-casting) overcomes many of the famili
ar limitations of sol-gel processing and permits the formation of low-cost,
crack-free, essentially zero-shrinkage ceramic bodies of complex shape. Th
ere are many potential industrial applications for the manufacture of compl
ex shapes by the freeze-gelation process. This paper presents the results o
f an investigation into the effects of materials and processing parameters
on the performance, properties and microstructures of the ceramics produced
. In particular, the effects on porosity and flexural strength of the type
and composition of sol, filler particle size ranges, and variable freezing
conditions, have been investigated.