Blends of maleated high density polyethylene with maleated EPDM

Citation
P. Antony et al., Blends of maleated high density polyethylene with maleated EPDM, KAUT GUM KU, 52(1), 1999, pp. 44-51
Citations number
31
Categorie Soggetti
Material Science & Engineering
Journal title
KAUTSCHUK GUMMI KUNSTSTOFFE
ISSN journal
09483276 → ACNP
Volume
52
Issue
1
Year of publication
1999
Pages
44 - 51
Database
ISI
SICI code
0948-3276(199901)52:1<44:BOMHDP>2.0.ZU;2-2
Abstract
Neutralisation of maleated high density polyethylene (mHDPE) with ZnO in th e presence of stearic acid results in an ionomeric plastic. Maleated EPDM ( mEPDM) similarly forms a rubbery ionomer in the same way. Blends of rubbery ionomer of mEPDM and ionomeric plastic based on mHDPE in ratios of 90/ 10 to 50/50 results in the formation of ionic thermoplastic elastomers, Ionome ric blends show higher tensile properties, tear resistance and hardness, bu t lower tension set than corresponding non-ionomeric EPDM/HDPE blends. The rubbery and plastic phases in the blends are immiscible, but the ionic inte ractions in the two phases facilitate formation of a technologically compat ible blend, Conclusions are based on the measurement of physical properties , IR spectroscopic, dynamic mechanical and recyclability studies.