Cluster carbonyls of Os, Fe and Fe-Rh on oxide supports: Synthesis and properties

Authors
Kuznetsov, BN Kovalchuk, VI Chesnokov, NV Mikova, NM Naimushina, LV
Citation
Bn. Kuznetsov et al., Cluster carbonyls of Os, Fe and Fe-Rh on oxide supports: Synthesis and properties, MACRO SYMP, 136, 1998, pp. 41-46
Citations number
13
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MACROMOLECULAR SYMPOSIA
ISSN journal
10221360 → ACNP
Volume
136
Year of publication
1998
Pages
41 - 46
Database
ISI
SICI code
1022-1360(199812)136:<41:CCOOFA>2.0.ZU;2-R
Abstract
Surface nano-size structures have been obtained by supporting on oxide supp orts (SiO2, MgO, Al2O3) some cluster carbonyls of Os, Fe, Fe-Rh and by thei r following thermal conversions. Surface species were characterized by IR-s pectroscopy, high-resolution TEM, XPS, Mossbauer spectroscopy and temperatu re-programmed desorption technique. Their catalytic properties was studied in CO hydrogenation reaction.