FTIR SPECTRA OF MATRIX-ISOLATED 2-METHYLBENZONORBORNEN-2-YL-TYPE CATIONS

Authors
VANCIK H GENAEV AM SHUBIN VG
Citation
H. Vancik et al., FTIR SPECTRA OF MATRIX-ISOLATED 2-METHYLBENZONORBORNEN-2-YL-TYPE CATIONS, Perkin transactions. 2, (4), 1997, pp. 667-668
Citations number
7
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Perkin transactions. 2 → ACNP
ISSN journal
03009580
Issue
4
Year of publication
1997
Pages
667 - 668
Database
ISI
SICI code
0300-9580(1997):4<667:FSOM2C>2.0.ZU;2-D
Abstract
FTIR spectra suggest that ionization of 2-exo-chloro-2-methylbenzonorb ornene dagger in an SbF5 matrix at -196 degrees C leads to 2-methyl-2- benzonortricyclyl cation which rearranges into a partially pi-bridged 2-methyibenzonorbornen-2-ylion at -123 degrees C.