METAL-ASSISTED REACTIONS .26. CATALYTIC REACTIVITY AND ETHER BOND LENGTHS IN ARYLOXYTETRAZOLES AND ARYLOXYPSEUDOSACCHARINS

Authors
ALVES JAC BARKLEY JV BRIGAS AF JOHNSTONE RAW
Citation
Jac. Alves et al., METAL-ASSISTED REACTIONS .26. CATALYTIC REACTIVITY AND ETHER BOND LENGTHS IN ARYLOXYTETRAZOLES AND ARYLOXYPSEUDOSACCHARINS, Perkin transactions. 2, (4), 1997, pp. 669-677
Citations number
39
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Perkin transactions. 2 → ACNP
ISSN journal
03009580
Issue
4
Year of publication
1997
Pages
669 - 677
Database
ISI
SICI code
0300-9580(1997):4<669:MR.CRA>2.0.ZU;2-6
Abstract
X-Ray structure determinations on a variety of aryloxytetrazoles 1 and aryloxypseudosaccharins 4 have shown that the central C-O-C ether lin kage is remarkable in having one very long C-O bond and one very short one. The central C-O-C bond angle is close to 120 degrees. The implic ations of these effects on the reactivity of compounds 1 and 4 towards catalytic hydrogenolysis or cross-coupling are explored.