ECLIPSED CONFORMATIONS FOR CARBON-OXYGEN BONDS IN METHOXY DERIVATIVESOF INOSITOLS, SUGARS AND SIMILAR COMPOUNDS

Authors
ANDERSON JE ANGYAL SJ CRAIG DC
Citation
Je. Anderson et al., ECLIPSED CONFORMATIONS FOR CARBON-OXYGEN BONDS IN METHOXY DERIVATIVESOF INOSITOLS, SUGARS AND SIMILAR COMPOUNDS, Perkin transactions. 2, (4), 1997, pp. 729-734
Citations number
44
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Perkin transactions. 2 → ACNP
ISSN journal
03009580
Issue
4
Year of publication
1997
Pages
729 - 734
Database
ISI
SICI code
0300-9580(1997):4<729:ECFCBI>2.0.ZU;2-9
Abstract
Eclipsing of exocyclic carbon-oxygen bonds in methyl ether derivatives of inositols and carbohydrates is reported and discussed. Structural fragments stereotypical for eclipsing are recognised, namely an axial or equatorial alkoxy group on a six-membered ring with equatorial subs tituents on either side, The X-ray crystal structure of hexa-O-methyl- epi-inositol is reported. Some analogous compounds which also have ecl ipsed bonds are reported.