Microscopic properties of B in ZnSe are investigated by means of beta-radia
tion-detected nuclear magnetic resonance (beta-NMR). After implantation of
spin-polarized, radioactive B-12 nuclei in nominally undoped ZnSe single cr
ystals at stationary concentrations of similar to 10(8) cm(-3), three diffe
rent B-defect configurations can be distinguished. First, an unperturbed fr
action at cubic lattice sites, identified as substitutional B-Zn(+) by a di
polar linewidth analysis. Second, a smaller part of. "perturbed" probes att
ributed also to B-Zn(+) but with nearby Se vacancies. And third, a paramagn
etic configuration, tentatively assigned to the isolated interstitial B-i(2
+) Temperature-dependent measurements shaw a conversion of B-i to B-Zn with
an activation energy of E-a = 0.61(3) eV which we attribute to B-i migrati
on. After this annealing stage we find a B-Zn fraction of about 85%, i.e.,
an excellent ''doping efficiency." A substantial inward relaxation of the n
earest: Se and next-nearest Zn atoms around the B-Zn(+) donor is observed a
nd compared with model predictions. [S0163-1829(99)05104-8].