The spontaneous ultraviolet luminescence reported [G. M. Irwin and K. H. Ki
m, Phys. Rev. Lett. 79, 990 (1997); D.S. Richardson et al., ibid. 80, 3206
(1998)] from (233)uranium compounds and ascribed to an ultraviolet gamma-ra
y emission from the metastable (229)thorium daughter is actually N-2 discha
rge emission induced in the air surrounding the sample by the sample radioa
ctivity. The UV spectrum from high elemental and isotopic purity (UO3)-U-23
3 reported here also exhibits a line at 391.3 nm that does not appear to be
due to electric discharge N-2 emission. [S0031-9007(99)08412-4].