Non-isothermal cooling during processing causes the development of residual
stresses, which are analyzed for compression molded UHMWPE, and affects th
e dimensional stability. The development of thermal residual stresses was p
redicted using an incremental stress analysis that included temperature-dep
endent material properties. Strain gauges were used to measure the residual
stresses as layers were removed from a molded disk using a Process Simulat
ed Laminate (PSL) approach. The PSL technique has not previously been appli
ed to a compression molded neat polymer. For initial surface cooling rates
of similar to 11 degrees C/min, the model predicted a compressive stress at
the bottom surface of 14 MPa and a tensile stress near the center of 2.5 M
Pa and matched the experimental distribution well. Because the compressive
residual stress was 70% of the yield strength (similar to 20 MPa), a lower
cooling rate was also tested (2.6 degrees C/min). The maximum tensile and c
ompressive stresses for this cooling rate were, 0.91 MPa and 2.5 MPa, respe
ctively. The model demonstrated its use for predicting thermal residual str
esses in compression molded parts, instead of trial-and-error experimentati
on. UHMWPE is shown to develop residual stresses continually from similar t
o 120 degrees C to 23 degrees C.