RADICAL CYCLIZATION WITH HIGH DIASTEREOFACIAL SELECTIVITY - ASYMMETRIC-SYNTHESIS OF (-12B-EPIDEVINYLANTIRHINE())

Authors
IHARA M KATSUMATA A FUKUMOTO K
Citation
M. Ihara et al., RADICAL CYCLIZATION WITH HIGH DIASTEREOFACIAL SELECTIVITY - ASYMMETRIC-SYNTHESIS OF (-12B-EPIDEVINYLANTIRHINE()), Journal of the Chemical Society. Perkin transactions. I, (7), 1997, pp. 991-992
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
7
Year of publication
1997
Pages
991 - 992
Database
ISI
SICI code
0300-922X(1997):7<991:RCWHDS>2.0.ZU;2-D
Abstract
Radical cyclisation of the chiral alpha,beta-unsaturated ester 1, carr ied out in the presence of MAD, gives six-membered cyclic acetal 2 dia stereoselectively, which is transformed into(+)-12b-epidevinylantirhin e 7.