The surface and bulk electronic excitations of CuGeO3 are investigated by m
eans of electron energy loss and polarized X-ray absorption spectroscopy. C
uGeO3 shows a surface charge transfer gap of about 3.0+/-0.3 eV. The unoccu
pied oxygen derived density of states, as probed by X-ray absorption at the
O 1s edge, is in good agreement with recent many-body calculations. (C) 19
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