Allylation of novel beta-phenylthio substituted gem-difluoroallylic bromide to carbonyl compounds

Authors
Jeong, IH Kim, MS Kim, BT
Citation
Ih. Jeong et al., Allylation of novel beta-phenylthio substituted gem-difluoroallylic bromide to carbonyl compounds, SYN COMMUN, 29(2), 1999, pp. 235-241
Citations number
14
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
29
Issue
2
Year of publication
1999
Pages
235 - 241
Database
ISI
SICI code
0039-7911(1999)29:2<235:AONBSG>2.0.ZU;2-N
Abstract
The reaction of beta-phenylthio substituted gem-difluoroallylic bromide 3 w ith aldehydes and ketones in the presence of Zn(Cu) in THF at reflux temper ature afforded the corresponding homoallylic alcohols 4 in good yields.