Pillared Buserite as a new catalytic material for the 1,3-dipolar cycloaddition of alpha-phenyl-N-(p-methyphenyl) nitrone with electron deficient olefins.

Authors
Ramamoorthy, V Ramasubbu, A Muthusubramanian, S Sivasubramanian, S
Citation
V. Ramamoorthy et al., Pillared Buserite as a new catalytic material for the 1,3-dipolar cycloaddition of alpha-phenyl-N-(p-methyphenyl) nitrone with electron deficient olefins., SYN COMMUN, 29(1), 1999, pp. 21-26
Citations number
17
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
29
Issue
1
Year of publication
1999
Pages
21 - 26
Database
ISI
SICI code
0039-7911(1999)29:1<21:PBAANC>2.0.ZU;2-M
Abstract
For the first time, synthetic polyoxoaluminium Keggin ion pillared Buserite (KPB), has been used as an effective catalytic material for the 1,3-dipola r cycloaddition reaction of alpha-N-diaryl nitrone such as alpha-phenyl-N-( p-methylphenyl) nitrone with some electron deficient olefins resulting in t he exclusive formation of trans-4-substituted isoxazolidines.