Trans-esterification in dry media using ferric perchlorate adsorbed on silica gel

Authors
Parmar, A Goyal, R Kumar, B Kumar, H
Citation
A. Parmar et al., Trans-esterification in dry media using ferric perchlorate adsorbed on silica gel, SYN COMMUN, 29(1), 1999, pp. 139-143
Citations number
16
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
29
Issue
1
Year of publication
1999
Pages
139 - 143
Database
ISI
SICI code
0039-7911(1999)29:1<139:TIDMUF>2.0.ZU;2-Z
Abstract
Adsorption of Fe(ClO4)(3)(H2O)(6) onto chromatographic grade silica gel in the presence of ethyl acetate (to be used for trans-esterification) produce s a supported reagent, Fe(ClO4)(3)(EtOAc)(6)/SiO2. This reagent has been fo und effective for the rapid and high yield of esters via trans-esterificati on on grinding in the presence of alcohols/carboxylic acids using pestle an d mortar in the solid state.