Silicon tethered ring-closing metathesis reactions for self- and cross-coupling of alkenols

Authors
Hoye, TR Promo, MA
Citation
Tr. Hoye et Ma. Promo, Silicon tethered ring-closing metathesis reactions for self- and cross-coupling of alkenols, TETRAHEDR L, 40(8), 1999, pp. 1429-1432
Citations number
30
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
8
Year of publication
1999
Pages
1429 - 1432
Database
ISI
SICI code
0040-4039(19990219)40:8<1429:STRMRF>2.0.ZU;2-W
Abstract
The title process can be used to couple allylic, homoallylic, and bishomoal lylic alkenols. Cyclic silaketals with ring sizes from 7-11 members can all be formed. This constitutes a general and versatile strategy for approxima tely doubling the molecular complexity of readily available alkenol precurs ors. (C) 1999 Elsevier Science Ltd. An rights reserved.