Cyclization/hydrosilylation of functionalized 1,7-dienes to form substituted six-membered carbocycles.

Authors
Stengone, CN Widenhoefer, RA
Citation
Cn. Stengone et Ra. Widenhoefer, Cyclization/hydrosilylation of functionalized 1,7-dienes to form substituted six-membered carbocycles., TETRAHEDR L, 40(8), 1999, pp. 1451-1454
Citations number
15
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
8
Year of publication
1999
Pages
1451 - 1454
Database
ISI
SICI code
0040-4039(19990219)40:8<1451:COF1TF>2.0.ZU;2-O
Abstract
The cationic palladium complex (phen)Pd(Me)(OEt2)(+) BAr4- [phen = I,10-phe nanthroline; Ar = 3,5-C6H3(CF3)(2)] catalyzed the cyclization/hydrosilylati on of functionalized 1,7-dienes to form silylated cyclohexanes in good yiel d and with moderate to good trans-selectivity. (C) 1999 Elsevier Science Lt d. All rights reserved.