M. Soustelle et M. Pijolat, EXPERIMENTAL METHODS USEFUL IN THE KINETIC MODELING OF HETEROGENEOUS REACTIONS, Solid state ionics, 95(1-2), 1997, pp. 33-40
A theorem on the separation of models is reported which shows how it m
ay be possible to describe the kinetics of a reaction involving a soli
d: a physico-chemical model in which 'reactivity' has been defined, an
d a geometrical model to which a 'space function' corresponds. Then a
series of rigorous experimental methods based on this theorem are pres
ented. Their use improves and validates the kinetic modelling of a het
erogeneous reaction.