F. Lebeau et al., SYNTHESIS OF BARIUM TITANIUM-OXIDE FROM BARIUM-SULFATE AND ANATASE - STUDY OF EQUIMOLAR MIXTURES UNDER DIFFERENT ATMOSPHERES, Solid state ionics, 95(1-2), 1997, pp. 151-154
To enable the ceramization of a barium sulphate-rich radioactive waste
the synthesis of barium titanium oxide is studied by using anatase an
d barium sulphate. As a function of the calcination atmosphere, helium
(or air) and Ar/H-2, two reactions are studied. A mechanism of barium
titanium oxide synthesis in helium (or in air) is proposed.