Synthesis and X-ray structure determination of iso-butylimido galliummethyl, [CH3Ga-NCH2CH(CH3)(2)](6)

Authors
Schmid, K Niemeyer, M Weidlein, J
Citation
K. Schmid et al., Synthesis and X-ray structure determination of iso-butylimido galliummethyl, [CH3Ga-NCH2CH(CH3)(2)](6), Z ANORG A C, 625(2), 1999, pp. 186-188
Citations number
15
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
625
Issue
2
Year of publication
1999
Pages
186 - 188
Database
ISI
SICI code
0044-2313(199902)625:2<186:SAXSDO>2.0.ZU;2-3
Abstract
The thermal decomposition of [Me2Ga-N(Bu-i)SnMe3](2) (prepared by the react ion of [(Me2SnNBu)-Bu-i](3) with GaMe3 in a 1:3 molar ratio) in an evacuate d, sealed tube at 160 degrees C forms [(MeGaNBu)-Bu-i](6) in high yield and SnMe4. Mass, H-1 and C-13 NMR as well as some IR and Raman spectroscopic d ata are given and the crystal structure of this cage molecule with a hexago nal prismatic Ga6N6 skeleton has been determined.